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Full Record Details
Persistent URL
http://purl.org/net/epubs/work/35172
Record Status
Checked
Record Id
35172
Title
The preparation and structures of hydrogen ordered phases of ice
Contributors
Christoph G Salzmann
,
Paolo G Radaelli
,
Andreas Hallbrucker
,
Erwin Mayer
,
John L Finney
Abstract
Two hydrogen ordered phases of ice were prepared by cooling the hydrogen disordered ices V and XII under pressure. Previous attempts to unlock the geometrical frustration in hydrogen-bonded structures have focused on doping with potassium hydroxide and have had success in partially increasing the hydrogen ordering in hexagonal ice I (ice Ih). By doping ices V and XII with hydrochloric acid, we have prepared ice XIII and ice XIV, and we analyzed their structures by powder neutron diffraction. The use of hydrogen chloride to release geometrical frustration opens up the possibility of completing the phase diagram of ice.
Organisation
CCLRC
,
ISIS
,
ISIS-GEM
,
ISIS-ILL
Keywords
Physics
,
Chemistry
,
ISIS 2006
Funding Information
Related Research Object(s):
Licence Information:
Language
English (EN)
Type
Details
URI(s)
Local file(s)
Year
Journal Article
Science
311 (2006): 1758-1761.
doi:10.1126/science.1123896
2006
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